A further life limiting factor is electrolyte water loss. VRLA batteries are designed to operate during their entire service life without any topping-up of the electrolyte with water. For this purpose, an oxygen recombination cycle is introduced so to reduce the loss of electrolyte water to a minimum.
However water loss does nevertheless occur and has following magnitudes:
- recombination efficiency < 100 % approx. 0.016 g per 100 Ah cell and day
- excessive float current 0.336 g per ampere hour excessive float current and cell
- positive grid corrosion 0.17 g per gram of lead oxydized to PbO cell case transpiration approx. 0.06 g per 100 Ah cell and day at +40¡ã C
- self discharge reaction approx. 0.0336 g per 100 Ah cell and day at 20 ¡ãc
Excessive water loss by one or more of the above mechanisms can cause the premature failure of a VRLA battery by a process called dry-out. Dry-out results in reduced electrolyte volume and capacity loss.